Apple Podcasts checks your RSS feed periodically. If your newest episode hasn't shown up, it's probably because they haven't refreshed your feed yet (typically, this happens every few hours). 

For example, even if you scheduled your episode to be published at 9 am, Apple still checks your feed on its own schedule.

You can manually force Apple to refresh your feed if you sign in to your Apple Podcast Connect account. Once you force a refresh it should start showing up everywhere.

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